As has been said, treatment-wise, give supportive treatment, including 02 as required, but make sure to call ahead as far as possible so the ER can get a negative pressure room ready (Including transferring a pt out of a negative pressure room if needed, since they're usually just used as regular rooms.)
Safety wise, every ambulance I've ever worked on (In the US), including the poorly equipped service I work for now, has at least 3 N95 masks (Not to be confused with surgical masks) on the rig, one for your partner, one for you and one for your pt (Remember, it's not just about keeping you and your partner safe, it's about keeping everyone in the hallway safe, too.). Supposedly N95 is effective against TB (I don't actually have any evidence to the contrary, I'm just suspect of anyone who tells me "This product will protect you!").
If you have a pt who you suspect of TB, and you feel they need high-flow O2, you won't have any real luck with throwing a NRB over a N95, the constriction of gas flow and the non-conformity of the masks will be too high, you'll need to throw a nasal cannula under the N95, but not up the nares, and crank it up high. You won't have a reservoir bag, which will limit the O2 delivered to the lungs, but it's better than nothing, and you'll sacrifice some of the seal on the N95, and with positive pressure to boot, you might want to seal around the tubing with some tape, but it's your best compromise.
All that being said, I've had exactly one pt in my career I went ahead and called suspected TB on, he was a nursing home pick up, complaining of coughing x 3 days, sitting in the middle of the TV room (Of course), and when I asked him, he said he was bringing up frank blood (I never saw it myself.) and that he had a hx of TB. Apparently within about 15 minutes of my getting him to the ER, they cleared him. (They also wondered what was keeping me it seems, since I called the very moment I heard about the blood and hx, rather than waiting until I actually was on the road.) As far as I'm concerned, I would rather cry wolf 100 times rather than miss crying the real deal once.