Personally, I'd defibrillate them. Doing CPR in the back of a moving ambulance is largely ineffective and very dangerous. For a cardiac arrest witnessed by ambulance personnel where a defibrillator is immediately available, what is the point in delaying delivering a shock in favour of CPR?
If somebody literally collapses in front of me in VF or VT, provided a defibrillator was immediately available and in manual mode, I'll give up to three sequential shocks before starting CPR. I know the regime of multiple shocks went out earlier in the century to single shocks at maximum joules, but somebody who literally fell over a few seconds ago is somebody you can likely revert with one or two shocks. With a defibrillator in manual mode, this is quick to achieve. I've had two witnessed cardiac arrests where ROSC has been obtained in one or two shocks.