I will start,
Our service has refilled the D size cylinders from 2 M size cylinders. This is done by cascadeing, (series of consecutive cylinders) labeled as 1st(CYL 1) and 2nd. (CYL 2)
The cylinder to be refilled(CYL 3) is attached to the 1st M size cyl(CYL 1), and the valve is very slowly opened on the CYL 1 to get a gauge reading from that cyl. then the valve is closed. (the pressure should hold steady. If so, then the D cylinder(cyl. 3) valve is slowly opened and the gauge is monitored. if the pressure decreases, Cyl 3 pressure is less therefore we will charge cyl. 3 with Cyl 1. This process "MUST" be done at a very slow rate. A high rate of refill will create heat, and this could very well result in a rupture of the Thermal relive valve (lead reinforced copper blowout disc).
When the both cylinder pressures are balanced, both valves are closed. The pressure in the connection fittings is released, and cyl 3 is then ready to be placed back into service if the pressure is 2000psi or more, or is then connected to cyl 2 (M size) and again cyl. 2 valve is slowly opened, then closed, holding the pressure (if pressure drops in tis stage, the connection between the cylinders need to be addresses(seal condition, tightness, index pin alignment, etc). Cyl 3 valve is slowly opened, and the gauge is checked for pressure (lower means cyl 3 need, pressure rises, Cyl 3 is already higher than cyl 2, pressure stays same(cyl 2 & 3 are equal).
The refilled cylinder must be assessed for heat, as a cyl may take several minuets to stabilize after filling(heat), If done properly, the cylinder temp, should rise very much. Any cylinder that heats to a point where its to hot to handle is improperly filled, and could be a danger to anyone or anything in close proximity.
This happened year ago with our Fire Department. A "D" cylinder was refilled(to fast) and put into the spare rack. aprox. 5 min after it was filled the thermal relive plug ruptured and the cylinder left the rack and spun around the fire hall, with about 10 firefighters dodging out of the way. It was a terrible racket and it hit the tires on several vehicles, but nobody was injured.
Upon inspection of the spare cylinders one more was found with lead protruding about 1/8 th inch out of the plugs release holes. (that cylinder was filled to fast before also).
Many services have discontinued this refill practice and elect to have a vendor service preform this need for them.