If they can't walk out, don scba and escort them out. The treatment for CO Poisoning is the same weather you're an EMT or Paramedic. The only exception in PA is that ALS can use different masks. BLS could use 15LPM O2 by A Non-Rebreating Mask, and ALS could use 15-20 LPM O2 by a Venturi or High Concentration. Depending on the severity of the effects, I may choose to use 25LPM CPAP.
Everyone would get atleast a saline lock, so I would have vein access to draw labs. If they were really out of it, then I'd probably do a 4 lead EKG workup, IV w/ NS, KVO; Glucose check is a standard test to rule out other reasons for their lethargy. Maybe some Lasix and Albuterol, as there is no exact treatment for CO poisoning other than lots of O2 real fast. At least not in my regional protocols. In severe cases, perhaps intubation is appropriate, as it is sometimes necessary to transport them via air to a facility w/ a Hyperbaric Chamber. 100% Oxygen in a pressurized chamber is usually the best treatment for severe CO Poisoning.
Never use the pulse ox.. I take it off if I get in and find a BLS unit using it, for any call, because they tend to treat what the monitor says. They can be grey and puffing for air, but if it has a false reading of 100, they don't use the oxygen.
** Not all of them do that, but I find that "brand new" EMT's use their pulse ox to treat and diagnose. While it is a helpful tool, it should not affect ones decision to put a patient on oxygen. Of course if they have COPD and you're more than 2 hours from an ED, I'd start out with high flow till they get their color back, then switch to their regular dose of Oxygen.. Maybe a few ticks higher. Always be ready to bag em.
As far as the home, and how to evacuate the gas..
If they don't have PPE, i.e. SCBA, keep them at least 100 feet away. Evac nearby homes in necessary. I tend to find that the gas meter will begin to pick up high levels of Co gas upto 30 feet from a house with high levels. If a fireman doesn't feel well, even if they didn't before they came, put him back in the apparatus w. a cylinder and a high concentration mask. Or transport, what ever your SOG is on that.
Our FD would go in w/ SCBA and check the readings with their own gas meter, open all the windows, open the flue, clean their chimney, and ensure that all is working properly. If it isn't, they call in one of the Business members of the Department who is certified to do the work necessary, and they repair the problem. The insurance company is billed for the work, if they won't pay, then it's free. Can't just open the windows and leave them without heat, pipes will freeze, and they may not be able to afford to have the necessary repairs made.